Here are the technical indicators (specifications) for HEDP•Na₄ (Tetrasodium Etidronate), a widely used scale and corrosion inhibitor in water treatment, oilfields, and industrial applications:
HEDP•Na₄ (Tetrasodium Etidronate) Technical Specifications
Parameter Standard Specifications Testing Method
Chemical Name Tetrasodium 1-Hydroxyethylidene-1,1-Diphosphonate —
CAS No. 3794-83-0 —
Molecular Formula C₂H₆O₇P₂Na₄ —
Appearance Colorless to light yellow transparent liquid Visual
Active Content ≥ 28.0% (as HEDP•Na₄) Titration (Na⁺)
pH (1% solution) 10.0–12.0 pH meter
Density (20°C) 1.30–1.40 g/cm³ Hydrometer
Phosphorus Content (as PO₄³⁻) ≥ 18.0% ICP/OES
Iron (Fe) Content ≤ 0.001% (10 ppm) AAS/ICP
Chloride (Cl⁻) ≤ 0.1% Titration
Solubility Fully soluble in water —
Thermal Stability Stable up to 100°C Heat aging test
Key Performance Features
High Chelating Ability – Strong binding with Ca²⁺, Mg²⁺, Fe²⁺/Fe³⁺, preventing scale formation.
Excellent Scale Inhibition – Effective against CaCO₃, CaSO₄, BaSO₄ scales.
Corrosion Inhibition – Forms a protective film on metal surfaces (carbon steel, copper).
Chemical Stability – Resists hydrolysis and chlorine attack (better than HEDP acid form).
Compatibility – Works well with polymers, zinc salts, and oxidizing biocides.
Comparison: HEDP•Na₄ vs. HEDP (Acid Form)
Property HEDP•Na₄ HEDP (Acid Form)
pH 10–12 (Alkaline) 1–2 (Acidic)
Solubility Higher in water Lower (requires neutralization)
Handling Safety Less corrosive Highly corrosive (needs PPE)
Storage Stable long-term May crystallize at low temps
Typical Applications
Cooling Water Treatment (5–30 ppm)
Oilfield Scale Inhibition (10–50 ppm in produced/injection water)
Textile & Detergent Industry (as a chelating agent)
Metal Surface Treatment (electroplating, pickling)
Packaging & Storage
25 kg, 200 kg plastic drums or 1000 kg IBC tanks.
Store in a cool, dry place (avoid freezing).
Shelf life: 12 months (unopened).
Safety & Environmental Data
Non-toxic, biodegradable (partial).
LD50 (oral, rat): >2000 mg/kg (low toxicity).
Compliance: Meets REACH, EPA, and OSPAR regulations.
Note: For specific formulations (e.g., with zinc or polymers), conduct compatibility tests before field application.
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