HEMPA (Hydroxyethylidene Diphosphonic Acid) is a highly effective phosphonate-based scale and corrosion inhibitor, commonly used in water treatment, oilfield applications, and industrial cleaning. Below is a guide on how to use HEMPA effectively:
1. Typical Applications of HEMPA
Scale Inhibition (CaCO₃, CaSO₄, BaSO₄, Fe₂O₃)
Corrosion Inhibition (for metals like steel, copper, and alloys)
Chelating Agent (binds to metal ions like Ca²⁺, Mg²⁺, Fe³⁺)
Oilfield Applications (prevents scale in drilling fluids & pipelines)
Industrial Cleaning (removes rust and mineral deposits)
2. Dosage Recommendations
The dosage depends on water chemistry and system conditions. General guidelines:
Application Dosage (ppm - parts per million)
Cooling Water Systems 5–20 ppm (continuous dosing)
Boiler Water Treatment 10–30 ppm
Oilfield Scale Inhibition 20–50 ppm
Industrial Cleaning 0.5–2% (by weight in cleaning solution)
Detergent Additive 0.1–1% (for chelation)
Note:
Higher dosages may be needed in high-hardness or high-iron water.
For closed-loop systems, lower doses (5–15 ppm) are often sufficient.
3. How to Apply HEMPA
A. Water Treatment (Cooling/Brine Systems)
Dilute HEMPA in water (if using concentrated acid form, neutralize with NaOH for better solubility).
Inject continuously via dosing pump into the water stream.
Monitor pH (optimal range: 6–9; adjust with alkali if needed).
Combine with other inhibitors (e.g., zinc, molybdate, or polymers like PAA for enhanced corrosion/scale control).
B. Oilfield Scale Control
Add to drilling fluids or injection water (20–50 ppm).
Works synergistically with phosphates or polyacrylates.
C. Industrial Cleaning
Mix 0.5–2% HEMPA with water and a surfactant.
Circulate or soak equipment to dissolve rust/mineral deposits.
Rinse thoroughly after cleaning.
4. Compatibility & Safety
Compatible with: Most polymers (e.g., PAA, PBTC), biocides, and oxidizing agents (at moderate levels).
Avoid mixing with: Strong acids (unless diluted) or high concentrations of hypochlorite (can degrade HEMPA).
Safety:
Wear gloves & goggles (mildly acidic).
Store in plastic containers (avoid metal corrosion).
Biodegradable but should be handled responsibly.
5. Advantages Over Alternatives
Better thermal stability than ATMP/EDTA.
Excellent scale inhibition at low dosages.
Works in high-pH and high-temperature conditions (up to 200°C).
6. When to Choose HEMPA Over HEDP?
If you need better Fe³⁺ stabilization (HEMPA is superior in high-iron water).
For high-temperature systems (HEMPA degrades slower than HEDP).
If cost is a concern (HEMPA is often cheaper than HEDP).
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