GLDA·Na₄ is a biodegradable, high-performance chelating agent that serves as an eco-friendly alternative to EDTA, NTA, and phosphonates. Below is a step-by-step guide on its applications, dosing, and best practices.
1. Key Properties of GLDA·Na₄
Chemical Name: Tetrasodium Glutamate Diacetate
CAS No.: 51981-21-6
Appearance: Clear to pale yellow liquid (or white powder for solid form)
Active Content: 38-40% (liquid), ≥90% (solid)
pH (1% solution): 10.5-12.0
Biodegradability: >90% (OECD 301B certified)
Key Advantages:
Strong chelation of Ca²⁺, Mg²⁺, Fe³⁺, Cu²⁺, Pb²⁺.
Works in high pH (up to 14) and high temperature (up to 100°C).
Non-toxic, eco-friendly (readily biodegradable, no aquatic toxicity).
Safe for food, cosmetics, and pharmaceuticals (meets ECOCERT, COSMOS standards).
2. Typical Applications & Dosage Recommendations
(1) Detergents & Cleaning Products
✅ Use Case:
Replaces phosphates and EDTA in laundry detergents, dishwashing liquids, and industrial cleaners.
Enhances surfactant performance by softening hard water.
📌 Dosage:
Liquid detergents: 1-5% (of final product).
Powder detergents: 2-10% (as a builder).
(2) Personal Care & Cosmetics
✅ Use Case:
Shampoos, soaps, creams (chelates metal ions to stabilize formulations).
Preservative booster (enhances efficacy of natural preservatives like benzyl alcohol).
📌 Dosage:
Skincare/haircare: 0.1-1.0%.
Oral care (toothpaste): 0.5-2.0%.
(3) Water Treatment
✅ Use Case:
Cooling/boiler water: Prevents CaCO₃, CaSO₄ scaling.
RO membrane cleaning: Removes metal fouling (Fe, Mn).
📌 Dosage:
Scale inhibition: 5-50 mg/L (depending on water hardness).
Membrane cleaning: 0.1-0.5% (with citric acid for pH adjustment).
(4) Agriculture & Fertilizers
✅ Use Case:
Micronutrient chelation (Fe, Zn, Mn) in liquid fertilizers.
Prevents nozzle clogging in fertigation systems.
📌 Dosage:
Fertilizer additive: 0.5-3.0% (based on nutrient content).
(5) Food & Beverage Industry
✅ Use Case:
Stabilizes color/flavor in juices, wines, and canned foods.
Prevents metal-catalyzed oxidation in edible oils.
📌 Dosage:
Beverages: 50-200 ppm.
Food processing: 0.01-0.1% (must comply with FDA/EFSA limits).
3. How to Apply GLDA·Na₄?
For Liquid Form (38-40%)
✔ Direct Use: Add as-is to formulations (no dilution needed).
✔ Dilution: Can be diluted with DI water (1:1 to 1:5) for easier handling.
For Solid Form (≥90% Powder)
✔ Dissolution:
Slowly add powder to warm water (40-60°C) under stirring.
Typical working solution: 10-20% aqueous solution.
4. Compatibility & Safety
✅ Works Well With:
Anionic/nonionic surfactants (SLES, CAPB, etc.).
Oxidizing agents (H₂O₂, peracetic acid).
Natural preservatives (levulinic acid, gluconolactone).
❌ Avoid Mixing With:
Strong acids (pH <3) → May reduce chelation efficiency.
High levels of Ca²⁺/Mg²⁺ → Pre-dilute to prevent precipitation.
⚠️ Safety Notes:
Skin/eye contact: Rinse with water (non-irritating but alkaline).
Storage: Keep in HDPE containers (avoid aluminum/steel for long-term storage).
5. Comparison with Other Chelators
Property GLDA·Na₄ EDTA NTA Citric Acid
Chelation Strength ★★★★★ ★★★★★ ★★★☆☆ ★★☆☆☆
Biodegradability >90% <5% ~40% 100%
pH Range 3-14 2-10 2-9 2-8
Cost Efficiency Medium High Low Low
Best For:
✔ Eco-friendly detergents (EU Ecolabel compliant).
✔ Food/cosmetic applications (safe for sensitive use).
✔ High-pH industrial systems (e.g., alkaline cleaning).
6. Storage & Shelf Life
Liquid: Store at 5-40°C, avoid freezing. (Shelf life: 12 months)
Solid: Keep in sealed, dry conditions. (Shelf life: 24 months)
Conclusion
GLDA·Na₄ is a versatile, sustainable chelator ideal for:
🌿 Green detergents & cosmetics
💧 Water treatment & membrane cleaning
🍏 Food stabilization & agriculture
For customized technical support, contact us for formulation advice!
TEL: +86-632-3671188
FAX: +86-632-3671189
E-mail: [email protected]
ADD: No.1, Fuqian South Road, Xuecheng Chemical Industrial Park, Xuecheng District, Zaozhuang City, Shandong Province, China