OAE-12 (N,N-di(hydroxyethyl) Dodecyl Amine Oxide) is a versatile surfactant and emulsifier with a unique combination of reactive and amphiphilic properties. Its primary applications are concentrated in a few key industries, with the paper and pulp industry being the most significant by far. Here's a breakdown of its primary industrial uses:
1. Paper and Pulp Industry (The Dominant Application)
This is the largest and most critical application for OAE-12. It serves as a key component in the production of Neutral Rosin Sizes (NRS) and, more importantly, as the primary emulsifier for Alkenyl Succinic Anhydride (ASA).
Role: Reactive Sizing Agent Emulsifier
Function:
Emulsification: Raw ASA is a water-insoluble oil. OAE-12 is used to emulsify it into a stable, fine-particle-size oil-in-water emulsion that can be easily mixed with paper pulp.
Sizing: The emulsified ASA, stabilized by OAE-12, is efficiently retained on the cellulose fibers. The anhydride group then reacts covalently with the hydroxyl groups on the fibers.
Benefit: This reaction makes the paper hydrophobic, providing resistance to water, ink, and other liquids. OAE-12-based emulsifiers are preferred for their:
Excellent Emulsion Stability: Prevents ASA from hydrolyzing too quickly before it can react with the fibers.
High Sizing Efficiency: Ensures uniform distribution and h3 bonding for superior and consistent paper quality.
Faster Curing: Compared to other sizing agents like AKD, ASA with OAE-12 cures almost instantly on the paper machine.
2. Agrochemicals Industry
OAE-12 is an effective emulsifier, dispersant, and wetting agent in various pesticide and herbicide formulations.
Role: Emulsifier and Stabilizer
Function: It helps create stable emulsifiable concentrates (ECs) and suspoemulsions (SEs). When the concentrate is diluted in the spray tank, OAE-12 ensures the active ingredients form a stable emulsion and disperse uniformly.
Benefit: Improves the application efficiency, coverage, and adhesion of agrochemicals on plant surfaces, leading to enhanced efficacy.
3. Coatings and Inks Industry
Its h3 dispersing capability makes it valuable in water-based formulations.
Role: Pigment Dispersant and Grinding Aid
Function: OAE-12 adsorbs onto the surface of organic and inorganic pigments (e.g., titanium dioxide, carbon black), preventing them from agglomerating. This creates stable, uniform dispersions with fine particle size.
Benefit: Results in coatings and inks with improved color strength, gloss, stability, and overall performance.
4. Textile Industry
It is used as a processing aid for fibers and yarns.
Role: Lubricant, Softener, and Anti-static Agent
Function: Reduces friction during high-speed spinning, weaving, and other mechanical processes.
Benefit: Improves processability, reduces fiber breakage, and imparts a soft hand-feel to the final fabric.
5. Construction Chemicals
It finds niche applications as an additive in cement and concrete.
Role: Air-entraining Agent and Plasticizer
Function: Introduces microscopic, stable air bubbles into the concrete mix.
Benefit: Significantly improves the freeze-thaw resistance of concrete by providing space for water to expand upon freezing, preventing cracking and scaling.
Summary Table of Primary Industries
Industry Primary Function of OAE-12 Key Benefit
Paper and Pulp Emulsifier for ASA Sizing Produces water-resistant paper efficiently and effectively.
Agrochemicals Emulsifier & Dispersant Stabilizes formulations, improves spray coverage and efficacy.
Coatings & Inks Pigment Dispersant Enhances color quality, stability, and gloss.
Textiles Lubricant & Softener Improves processing and final fabric hand-feel.
Construction Air-entraining Agent Increases concrete durability against freeze-thaw cycles.
In conclusion, while OAE-12 is used in several industries, its role as the critical emulsifier for ASA sizing in the paper industry is its most important and widespread application. Its ability to create reactive, stable emulsions is unmatched in this field.
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